• 文献标题:   Facile preparation of PtPdPt/graphene nanocomposites with ultrahigh electrocatalytic performance for methanol oxidation
  • 文献类型:   Article
  • 作  者:   XIE WF, ZHANG FF, WANG ZH, YANG M, XIA JF, GUI RJ, XIA YZ
  • 作者关键词:   ptpdpt/graphene nanocomposite, electrodeposition, catalyst, methanol oxidation, co tolerance
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Qingdao Univ
  • 被引频次:   24
  • DOI:   10.1016/j.jelechem.2015.12.007
  • 出版年:   2016

▎ 摘  要

In the present work, the PtPdPt nanocomposites with an average diameter of 22.3 nm are successfully anchored onto graphene nano-sheets by using a facile electrodeposition process, as advanced direct methanol fuel cell (DMFC) electrocatalysts. The resulting PtPdPt/graphene nanocomposites are developed toward highly active catalysts for methanol oxidation. Experimental results reveal that the PtPdPt/graphene catalysts exhibit significantly enhanced electrocatalytic performance (j(p) = 25.63 mA cm(-2)) and higher tolerance to carbon monoxide poisoning (I-F/I-B = 1.602) generates in the process of methanol oxidation when compared with traditional Pt/graphene (j(p) = 7.20 mA cm(-2); I-F/I-B = 1.178) and PtPd/graphene catalysts (j(p) = 12.86 mA cm(-2); I-F/I-B = 1.442). This study implies that the prepared catalysts have great potential applications in direct methanol fuel cells. (C) 2015 Elsevier B.V. All rights reserved.