• 文献标题:   Electrodeposition of Pt-Fe(III) Nanoclusters on Graphene Modified Glassy Carbon Electrode for Sensitive Detection of Nitrite
  • 文献类型:   Article
  • 作  者:   YANG XS, CUI X, LI YX
  • 作者关键词:   nitrite, pt, fe iii, nanocluster, graphene, electrochemical sensor
  • 出版物名称:   NANOSCIENCE NANOTECHNOLOGY LETTERS
  • ISSN:   1941-4900 EI 1941-4919
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   7
  • DOI:   10.1166/nnl.2015.1917
  • 出版年:   2015

▎ 摘  要

A novel electrochemical sensor for the detection of nitrite was fabricated by co-deposition of Pt nanoparticles and Fe(III) on reduced graphene oxide (RGO) modified glassy carbon electrode (GCE). Field emission scanning electron microscope (FE-SEM), transmission electron microscopy (TEM), and electrochemical techniques were used to characterize the structure of these nanocomposites. Electrochemical results showed that the Pt-Fe(III)/RGO/GCE exhibited remarkable electrocatalytic activity toward the oxidation of nitrite in phosphate buffer solution (pH 4.0). Under the optimum conditions, the linear range for the detection of nitrite was 4.0x10(-6) to 2.5x10(-4) M and a low detection limit of 6.0x10(-7) M. The proposed method was successfully applied in the detection of nitrite in salt samples.