• 文献标题:   MOF-derived, N-doped porous carbon coated graphene sheets as high-performance anodes for lithium-ion batteries
  • 文献类型:   Article
  • 作  者:   LIU X, ZHANG SC, XING YL, WANG SB, YANG PH, LI HL
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:   Beijing Univ Aeronaut Astronaut
  • 被引频次:   16
  • DOI:   10.1039/c6nj01896c
  • 出版年:   2016

▎ 摘  要

N-doped porous carbon coated graphene ( rGO) sheets ( denoted as NPCGS) have been synthesized through a facile pyrolysis of an in situ grown zeolitic imidazolate framework ( ZIF) on graphene oxide ( GO). When tested as an anode material for lithium-ion batteries, the NPCGS exhibited superior electrochemical performance with a specific capacity of 1040 mA h g(-1) after 200 cycles at a discharging current density of 0.5 A g(-1) and excellent rate performance. The fascinating electrochemical performance of the NPCGS can be attributed to the synergistic effect of NPC and graphene in terms of N-doping, rich porosity and high electrical conductivity. The novel N-doped porous carbon coated graphene sheet material can be extended for application in sensors, electronic devices, catalysts, hydrogen storage and other systems.