• 文献标题:   Graphene nanoplatelets thickness and lateral size influence on the morphology and behavior of epoxy composites
  • 文献类型:   Article
  • 作  者:   PROLONGO SG, JIMENEZSUAREZ A, MORICHE R, URENA A
  • 作者关键词:   polymer matrix composites pmcs, thermosetting resin, microstructure, thermomechanical
  • 出版物名称:   EUROPEAN POLYMER JOURNAL
  • ISSN:   0014-3057 EI 1873-1945
  • 通讯作者地址:   Univ Rey Juan Carlos
  • 被引频次:   32
  • DOI:   10.1016/j.eurpolymj.2014.01.019
  • 出版年:   2014

▎ 摘  要

Graphene nanoplatelets/epoxy nanocomposites were prepared using a high shear toroidal mixer as dispersion technique. Suitable dispersions were obtained. Several graphene nanoplatelets, with different thickness and lateral dimensions, were added in order to analyze the influence of these parameters in the final properties. An important nanofiller concentration gradient was found from the top to the bottom in nanocomposites reinforced with large nanoplatelets due to a natural deposition by gravity. This phenomenon is not appreciable when the nanoplatelets size decreased. However, the small nanoplatelets have a greater tendency to agglomerate in packages of several parallel particles. In general, graphene nanoplatelets addition caused an increment in glass transition temperature, stiffness and thermal stability compared to the epoxy resin. However, it was also found that graphene nanoplatelets dimensions significantly affect to these enhancements. Nanocomposites reinforced with larger and thicker nanoplatelets presented lower glass transition temperature, higher modulus and higher decomposition temperature. (C) 2014 Elsevier Ltd. All rights reserved.