• 文献标题:   Sealing of through-holes on hollow glass bubbles with graphene oxide
  • 文献类型:   Article
  • 作  者:   ZHANG H, BAO CL, YANG JL
  • 作者关键词:   hollow glass bubbles hgbs, graphene oxides g0s, throughhole, polydopamine pda
  • 出版物名称:   COLLOIDS SURFACES APHYSICOCHEMICAL ENGINEERING ASPECTS
  • ISSN:   0927-7757 EI 1873-4359
  • 通讯作者地址:   Hong Kong Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1016/j.colsurfa.2018.09.053
  • 出版年:   2018

▎ 摘  要

In this study, hollow glass bubbles (HGBs) of about 70 pm with through-holes of about 5 pm were successfully separated from a commercialized product and were used as targets to be sealed/covered by GO sheets of size about 24 mu m. Firstly, these HGBs were treated with poly(ethyleneimine) (PEI) cross-linked polydopamine (PDA) to positively charge their outer surface. After treatment, the outer surface of HGBs was uniformly deposited with PDA nano-particles. During sealing/covering process, GO sheets were successfully attracted to the PDA modified HGBs by electrostatic force between the negatively charged GO sheets and positively charged HGBs introduced by the deposited PDA nano-particles, and were anchored by PDA nano-particles at the outer surface to avoid sucking of GO sheets into HGBs through the holes. While most of HGBs were tightly sealed/covered, some of them were partially sealed due to the fractured or collapsed GO sheets on the through-holes.