• 文献标题:   Realization of Ambient-Stable Room Temperature Ferromagnetism by Low-Temperature Annealing of Graphene Oxide Nanoribbons
  • 文献类型:   Article
  • 作  者:   FU L, WANG Y, ZHANG KY, ZHANG WL, CHEN J, DENG Y, DU YW, TANG NJ
  • 作者关键词:   roomtemperature ferromagnetism, ambient stability, graphene oxide nanoribbon, lowtemperature annealing
  • 出版物名称:   ACS NANO
  • ISSN:   1936-0851 EI 1936-086X
  • 通讯作者地址:   Nanjing Univ
  • 被引频次:   7
  • DOI:   10.1021/acsnano.9b01542
  • 出版年:   2019

▎ 摘  要

Graphene oxide nanoribbons (GONRs) annealed at the low temperature of 400 degrees C (aGONRs-400) are developed as an excellent room-temperature (RT) ferromagnet. The saturated magnetization (M-s) of aGONRs-400 is high, up to 0.39 emu/g at room temperature, and the RT ferromagnetism (FM) exhibits excellent ambient stability with M-s preserved for over half a year. The preferential distribution of the magnetic phenolic hydroxyl toward the edges, which contributes to the long-range ferromagnetic couplings, was confirmed by X-ray photoemission spectroscopy measurement and gradient annealing analysis. The approach of low-temperature annealing is proved to be efficient both to remove the prominent nonmagnetic epoxy groups on the basal plane of GONRs or transform them to magnetic hydroxyl groups and to preserve the magnetic phenolic hydroxyl at the edges to realize a strong and ambient stable FM.