• 文献标题:   Cobalt sulfide supported on nitrogen and sulfur dual-doped reduced graphene oxide for highly active oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   ZHANG Y, LI PW, YIN XY, YAN Y, ZHAN K, YANG JH, ZHAO B
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Univ Shanghai Sci Technol
  • 被引频次:   10
  • DOI:   10.1039/c7ra09231h
  • 出版年:   2017

▎ 摘  要

Cobalt sulfide nanoparticles grown on nitrogen and sulfur dual-doped reduced graphene oxide sheets (CoS/ NS-rGO) were synthesized as an efficient electrocatalyst for the oxygen reduction reaction (ORR) by a facile one-step annealing process at 400-600 degrees C. The catalyst synthesized at 500 degrees C (Co-S/NS-rGO500) exhibits the best ORR catalytic activity compared to the other samples, together with high fourelectron selectivity and excellent stability in alkaline medium. Moreover, the Co-S/NS-rGO-500 composite also manifests good ORR activity and selectivity in acid solution. The facile synthesis approach and superior ORR performance in both alkaline and acid electrolytes make the Co-S/NS-rGO catalysts promising as an alternative to commercial Pt/C catalyst for fuel cells.