• 文献标题:   Preparation of SnO2 nanorods on reduced graphene oxide and sensing properties of as-grown nanocomposites towards hydrogen at low working temperature
  • 文献类型:   Article
  • 作  者:   REN HB, GU CP, JOO SW, CUI JY, SUN YF, HUANG JR
  • 作者关键词:   tin dioxide, rgo, freezedrying method, hydrogen, gas sensor, low working temperature
  • 出版物名称:   MATERIALS EXPRESS
  • ISSN:   2158-5849 EI 2158-5857
  • 通讯作者地址:   Anhui Normal Univ
  • 被引频次:   1
  • DOI:   10.1166/mex.2018.1428
  • 出版年:   2018

▎ 摘  要

SnO2@ reduced graphene oxide (SnO2@ rGO) nanocomposites are prepared using a freeze-drying method followed by heat treatment. The structure and morphology of the nanocomposites are characterized by X-ray diffraction, scanning electron microscopy, transmission electron microscopy, Raman spectra, and X-ray photoelectron spectroscopy. A large number of small uniform SnO2 nanorods are successfully anchored on the surface of the rGO nanosheet, and a p-n junction is formed at their interface. In addition, the gas-sensing properties of SnO2@ rGO are tested using different concentrations of H-2 at a low operating temperature of 80 degrees C. The SnO2@ rGO sensor exhibits outstanding gas-sensing properties towards H-2, such as fast response and recovery, high sensitivity, selectivity, and stability. The sensor response to 1% H-2 at 80 degrees C was approximately 1.58, and the response and recover times were 15 s and 61 s, respectively. The satisfactory gas-sensing performance can be attributed to the large specific surface area, high electrical conductivity and width of the electron depletion layer. A possible gas-sensing mechanism is also proposed.