▎ 摘　　要

In this work, reduced graphene oxide (RGO) -carbon nanotubes (CNT) grown on carbon fiber (CF) is fabricated by a combination of electrophoretic deposition (EPD) and chemical vapor deposition (CVD). Firstly, CF-GO composite is prepared via EPD. Secondly, the CF-RGO-CNT hybrid is obtained by floating catalyst chemical vapor deposition method for synthesizing CNT on the CF-RGO substrate. The as prepared three-dimensional (3D) hierarchical hybrid shows strong mechanical stability and high flexibility at various bending angles. Furthermore, the hybrid is characterized by scanning electron microscope, X-ray Diffraction and Raman spectroscopy, and its supercapacitor properties are also tested. The electrochemical measurements display a higher specific capacitance of 203 F g(-1), 4 times higher than that of pure CF. Importantly, the hybrid shows high electrochemical stability at various bending angles, and can be directly served as flexible electrode with binder-free for high-performance supercapacitors. All these attractive results indicate that the as-prepared 3D hybrid is a promising candidate for flexible supercapacitor applications. (C) 2017 Elsevier Ltd. All rights reserved.