• 文献标题:   Quasi- freestanding" Graphene- on- Single Walled Carbon Nanotube Electrode for Applications in Organic Light- emitting Diode
  • 文献类型:   Article
  • 作  者:   LIU YP, JUNG E, WANG Y, ZHENG Y, PARK EJ, CHO SM, LOH KP
  • 作者关键词:   single walled carbon nanotubes array, fewlayer graphene, transparent conductive film, quasifreestanding, organic lightemitting diode
  • 出版物名称:   SMALL
  • ISSN:   1613-6810 EI 1613-6829
  • 通讯作者地址:   Sungkyunkwan Univ SKKU
  • 被引频次:   16
  • DOI:   10.1002/smll.201301829
  • 出版年:   2014

▎ 摘  要

An air-stable transparent conductive film with quasi-freestanding graphene supported on horizontal single walled carbon nanotubes (SWCNTs) arrays is fabricated. The sheet resistance of graphene films stacked via layer-by-layer transfer (LBL) on quartz, and modified by 1-Pyrenebutyric acid N-hydroxysuccinimide ester (PBASE), is reduced from 273 /sq to about 76 /sq. The electrical properties are stable to heat treatment (up to 200 oC) and ambient exposure. Organic light-emitting diodes (OLEDs) constructed of this carbon anode (T approximate to 89.13% at 550 nm) exhibit approximate to 88% power efficiency of OLEDs fabricated on an ITO anode (low turn on voltage approximate to 3.1 eV, high luminance up to approximate to 29 490 cd/m(2), current efficiency approximate to 14.7 cd/A). Most importantly, the entire graphene-on-SWCNT hybrid electrodes can be transferred onto plastic (PET) forming a highly-flexible OLED device, which continues to function without degradation in performance at bending angles >60 degrees.