• 文献标题:   Precise In Situ Modulation of Local Liquid Chemistry via Electron Irradiation in Nanoreactors Based on Graphene Liquid Cells
  • 文献类型:   Article
  • 作  者:   WANG CH, SHOKUHFAR T, KLIE RF
  • 作者关键词:  
  • 出版物名称:   ADVANCED MATERIALS
  • ISSN:   0935-9648 EI 1521-4095
  • 通讯作者地址:   Univ Illinois
  • 被引频次:   14
  • DOI:   10.1002/adma.201602273
  • 出版年:   2016

▎ 摘  要

A controlled electron-water radiolysis process is used to generate predictable concentrations of radical and ionic species in graphene liquid cells, allowing the concept of a nanoscale chemical reactor. A differential scanning technique is used to generate the desired time- and space-varying electron dose rate. Precise control of the local concentration of H-2, the dominant radiolysis species, is demonstrated experimentally at the nanometer scale.