• 文献标题:   Efficient conversion of fructose into 5-hydroxymethylfurfural over WO3/reduced graphene oxide catalysts
  • 文献类型:   Article
  • 作  者:   HAN HT, ZHAO HY, LIU Y, LI ZF, SONG JY, CHU WY, SUN ZZ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Heilongjiang Univ
  • 被引频次:   15
  • DOI:   10.1039/c6ra26309g
  • 出版年:   2017

▎ 摘  要

A sustainable and efficient catalyst for converting carbohydrates to a renewable platform chemical 5-hydroxymethylfurfural (HMF) is the goal in the study of biomass recycling. Reduced graphene oxidesupported tungsten trioxide (WO3/RGO) as an acidic catalyst was synthesized through a one-step hydrothermal method, characterized via TEM, XPS, XRD and Raman spectroscopy and applied to the conversion of fructose to HMF. The WO3/RGO catalyst showed a highly efficient catalytic activity, and the yield of HMF could reach up to 84.2% with complete conversion of fructose. The catalyst could be reused five times with a slight decrease in activity. Further study indicated that WO3/RGO could also catalyze the conversion of cellulose, glucose and sucrose to HMF.