• 文献标题:   Facile synthesis of monodispersed Pd nanocatalysts decorated on graphene oxide for reduction of nitroaromatics in aqueous solution
  • 文献类型:   Article
  • 作  者:   ZHANG KQ, HONG K, SUH JM, LEE TH, KWON O, SHOKOUHIMEHR M, JANG HW
  • 作者关键词:   graphene oxide, nanocatalyst, nitroaromatic, palladium, reduction
  • 出版物名称:   RESEARCH ON CHEMICAL INTERMEDIATES
  • ISSN:   0922-6168 EI 1568-5675
  • 通讯作者地址:   Seoul Natl Univ
  • 被引频次:   33
  • DOI:   10.1007/s11164-018-3621-8
  • 出版年:   2019

▎ 摘  要

We synthesized the reproducible heterogeneous catalyst of graphene oxide (GO)-supported palladium nanoparticles (NPs) via a simple and green process. The structure, morphology and physicochemical properties of the synthesized heterogeneous catalyst were characterized by the latest techniques such as high-resolution transmission electron microscopy (TEM), scanning TEM, energy-dispersive X-ray spectroscopy, X-ray diffraction analysis, and X-ray photoelectron spectroscopy. The GO-supported Pd NPs (Pd/GO nanocatalyst) exhibited excellent catalytic activity for the reduction of nitroaromatics to aminoaromatics in aqueous sodium borohydride. The nitroaromatics were converted to corresponding aminoaromatics with high yields (up to 99%) using Pd/GO nanocatalyst in aqueous solution. The hybrid heterogeneous catalyst showed 83% of conversion after six cycles in the reduction of nitrobenzene to aminobenzene. These features ensured the high catalytic activity of the introduced graphene oxide supported Pd nanocatalysts.\ [GRAPHICS]