• 文献标题:   A nanoflower shaped gold-palladium alloy on graphene oxide nanosheets with exceptional activity for electrochemical oxidation of ethanol
  • 文献类型:   Article
  • 作  者:   WANG QY, CUI XQ, GUAN WM, ZHANG XM, LIU C, XUE TY, WANG HT, ZHENG WT
  • 作者关键词:   alloy, graphene, nanostructure, catalyst
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Jilin Univ
  • 被引频次:   20
  • DOI:   10.1007/s00604-013-1119-z
  • 出版年:   2014

▎ 摘  要

We report on a new and facile method for the preparation of well-dispersed gold-palladium (AuPd) flower-shaped nanostructures on sheets of graphene oxide (GO). Transmission electron microscopy and high angle annular dark field STEM were used to characterize the morphology and composition of the new nanohybrids. The AuPd/GO composites display high electrocatalytic activity for the oxidation of ethanol in strongly alkaline medium as examined by cyclic voltammetry and chronoamperometry. Both the current density (13.16 mA center dot cm(-2) at a working potential of -0.12 V) and the long-time stability are superior to a commercial Pd-on-carbon catalyst which is attributed to the cooperative action of the catalytic activities of Au and Pd, and the good dispersion of the alloy on the nanosheets.