• 文献标题:   Facile synthesis and capacitive performance of Cu@Cu2O/graphene nanocomposites
  • 文献类型:   Article
  • 作  者:   LI Y, WANG Q, LIU PP, YANG XH, DU GX, LIU Y
  • 作者关键词:   composite, capacitor, graphene, cu@cu2o
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Tianjin Normal Univ
  • 被引频次:   12
  • DOI:   10.1016/j.ceramint.2014.11.091
  • 出版年:   2015

▎ 摘  要

Cu@Cu2O/graphene nanocomposite was successfully synthesized by a facile one-step solovothermal approach. The in-situ formed Cu@Cu2O nanoparticles were homogeneously anchored onto graphene oxide sheets, which were simultaneously reduced directly to form the graphene sheets, and the nanoparticles acted as the spacers to avoid the neighboring graphene sheets aggregating or restacking. The composite exhibits a specific capacitance of 100.9 F/g at 0.1 A/g, which is higher than that of Cu@Cu2O nanoparticles (33.4 F/g). More importantly, the specific capacitance increases to 257 F/g after 1000 cycles at 0.1 A/g due to the electrochemical activation. The facile synthesis method and good electrochemical properties indicate that the nanocomposite could be a promising potential electrode candidate for supercapacitors. (C) 2014 Elsevier Ltd and Techna Group S.r.l. All rights reserved.