• 文献标题:   Facile synthesis of graphene-molybdenum dioxide and its lithium storage properties
  • 文献类型:   Article
  • 作  者:   SENG KH, DU GD, LI L, CHEN ZX, LIU HK, GUO ZP
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Univ Wollongong
  • 被引频次:   45
  • DOI:   10.1039/c2jm32822d
  • 出版年:   2012

▎ 摘  要

Graphene-molybdenum dioxide composites in several ratios have been prepared through a facile synthesis method. Depending on the ratio, the as synthesized composites have either 2-dimensional graphene sheets with MoO2 particles anchored to them or a clustered agglomerate morphology. The composites have been characterised using Raman spectroscopy, X-ray diffraction, and electron diffraction to confirm the monoclinic MoO2 phase that is present. Lithium storage properties of the as-synthesised samples were tested in a coin-type half cell assembly to determine the relationship between the ratio and the electrochemical performance. The sample with highest amount of MoO2 (78 wt%) displayed the most promising lithium storage properties, with stable cycling performance at 0.2 A g(-1) that shows negligible capacity loss over 50 cycles, retaining a capacity of 640 mA h g(-1). The rate capabilities were also tested, and show a capacity of 380 mA h g(-1) at 2.0 A g(-1), which is comparable to the theoretical capacity of graphite and previously reported work on similar materials.