• 文献标题:   Reduced graphene oxide catalysts for efficient regeneration of cobalt-based redox electrolytes in dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   GIANNOURI M, BIDIKOUDI M, PASTRANAMARTINEZ LM, SILVA AMT, FALARAS P
  • 作者关键词:   dyesensitized solar cell, cobalt redox couple, reduced graphene oxide, vitamin c, counter electrode
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   NCSR Demokritos
  • 被引频次:   7
  • DOI:   10.1016/j.electacta.2016.10.013
  • 出版年:   2016

▎ 摘  要

Efficient and low cost reduced graphene oxide (rGOV) is prepared by chemical reduction of graphene oxide (GO) using vitamin C. Detailed characterization by XRD, SEM and Raman techniques confirm the successful reduction of GO. Thin films of rGOV with various thickness are deposited by spin coating on FTO glass substrates and are used as counter electrodes (CEs) in dye-sensitized solar cells (DSCs) incorporating the organic sensitizer D35 dye and the Co(bpy)(3)(3+)/Co(bpy)(3)(2+) redox couple. These devices present high photocurrent density (j(sc)) and open-circuit voltage (V-oc) values resulting in enhanced photovoltaic performance in comparison with the Pt catalyst. The novel rGOV electrodes constitute an excellent, low-cost and environmentally friendly alternative solution to the costly platinum-based cathodes. (C) 2016 Elsevier Ltd. All rights reserved.