• 文献标题:   Graphene-based nanohybrid materials as the counter electrode for highly efficient quantum-dot-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   DAO VD, CHOI Y, YONG K, LARINA LL, CHOI HS
  • 作者关键词:  
  • 出版物名称:   CARBON
  • ISSN:   0008-6223 EI 1873-3891
  • 通讯作者地址:   Chungnam Natl Univ
  • 被引频次:   44
  • DOI:   10.1016/j.carbon.2014.12.014
  • 出版年:   2015

▎ 摘  要

Dry plasma reduction is an excellent approach for easily and uniformly immobilizing Pt, Au and bimetallic AuPt nanoparticles (NPs) on a graphene nanoplatelets (GC)-coated layer under atmospheric pressure at a low temperature and without using any toxic reductants. The NPs with an average size of about 2 nm were stably and uniformly hybridized on the surface of reduced graphene nanoplatelets (RGC) after co-reduction of metal precursor ions and GC to metal atoms and RGC, respectively. Quantum-dot-sensitized solar cells exploiting AuNP/RGC, PtNP/RGC and bimetallic AuPtNP/RGC counter electrodes (CEs) exhibited power conversion efficiencies of 2.7%, 3.0% and 4.5%, respectively. The efficiencies are comparable to that of device with a conventional Au-sputtered CE (3.6%). The effect is ascribed to high electrochemical catalytic activity and high electrical conductivity of developed nanohybrid materials. (C) 2014 Elsevier Ltd. All rights reserved.