• 文献标题:   Influence of gold nanoholes and nanoslits arrays on Raman spectra and optical reflectance of graphene oxide
  • 文献类型:   Article
  • 作  者:   QUISPE LT, MENEZES JW, CHONG W, ZEGARRA LBR, ARMAS LEG
  • 作者关键词:  
  • 出版物名称:   OPTICS EXPRESS
  • ISSN:   1094-4087
  • 通讯作者地址:   Univ Fed Santa Catarina
  • 被引频次:   0
  • DOI:   10.1364/OE.26.031253
  • 出版年:   2018

▎ 摘  要

We report the effect of gold nanostructured substrates, fabricated by interference lithography technique (IL), on the Raman spectra and optical reflectance of graphene oxide (GO) layers. For purposes of comparison two gold nanostructured substrates, nanoslits (AuNSs) and circular nanoholes (AuNHs) were compared with a non-nanostructured gold substrate. Effects induced by the gold nanostructured substrates are discussed in terms of the I-D/I-G ratio and the FWHM of the G band (FWHM(G)) as a function of the G band intensity (I-G), showing that both I-D/I-G and FWHM(G) parameters are highly sensitive to the number of GO layers (n(GO)), which would allow to identify the number of GO layers in a reliable way. Optical reflectance spectra (R(lambda)) reveal that plasmons are generated on the surface of nanostructured substrates by the incident radiation. Dips in R(lambda) are ascribed as coupling by surface plasmon polaritons described by Bloch waves (BW-SPP). A peak in R(lambda) is also observed and it is ascribed to visible radiation produced by FOrster resonance energy transfer and Purcell effect. The relevance of these results lies in the possibility of designing colorimetric plasmonic sensors, based on few layers of GO with an excellent control of n(GO) and with potential in detection of molecules by fluorescent absorption. (C) 2016 Optical Society of America under the terms of the OSA Open Access Publishing Agreement