• 文献标题:   Electrochemical Detection of Trace Amounts of Arsenic (III) in Poultry Using a Graphene Oxide-Bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)Cobalt Composite Modified Electrode
  • 文献类型:   Article
  • 作  者:   RAMANATHAN S, ELANTHAMILAN E, OBADIAH A, DURAIRAJ A, SANTHOSHKUMAR P, MERLIN JP, RAMASUNDARAM S, VASANTHKUMAR S
  • 作者关键词:   goco dip composite, bis 2 4, 5diphenyl1himidazol2yl phenoxy cobalt dip, voltammetry, electrochemical, broiler meat
  • 出版物名称:   JOURNAL OF ELECTRONIC MATERIALS
  • ISSN:   0361-5235 EI 1543-186X
  • 通讯作者地址:   Karunya Univ
  • 被引频次:   0
  • DOI:   10.1007/s11664-019-07233-3
  • 出版年:   2019

▎ 摘  要

This paper reports the electrochemical sensing of trace amounts of arsenic (As (III)) in broiler meat using a graphene oxide-bis(2-(4,5-diphenyl-1H-imidazol-2-yl)phenoxy)cobalt composite (GO-Co (DIP)) composite modified electrode. The synthesized nanocomposite was characterized by Fourier transform infrared spectrometry, x-ray diffraction and scanning electron microscopy techniques. The electrochemical studies were carried out by cyclic and pulse voltammetry techniques. To detect the trace amount of As (III) with a highest sensing ability, optimization of some of the analytical factors such as pH, scan rate, deposition time, concentration, pulse height and pulse width were carried out. Employing optimized conditions, the oxidation peak current of As (III) was obtained in the range from -1.0 V to 1.0V and it exhibited a very low detection limit of 0.04M. The developed GO-Co (DIP) composite modified electrode was used to detect the trace amount of As (III) in broiler meat and a comparison was also carried out with the meat of native breeds.