• 文献标题:   Sodium alginate/graphene oxide aerogel with enhanced strength-toughness and its heavy metal adsorption study
  • 文献类型:   Article
  • 作  者:   JIAO CL, XIONG PG, TAO J, XU SJ, ZHANG DS, LIN H, CHEN YY
  • 作者关键词:   sodium alginate, graphene oxide, aerogel, strength, toughnes, adsorption
  • 出版物名称:   INTERNATIONAL JOURNAL OF BIOLOGICAL MACROMOLECULES
  • ISSN:   0141-8130 EI 1879-0003
  • 通讯作者地址:   Soochow Univ
  • 被引频次:   61
  • DOI:   10.1016/j.ijbiomac.2015.11.061
  • 出版年:   2016

▎ 摘  要

Ordered porous sodium alginate/graphene oxide (SAGO) aerogel was fabricated by in situ crosslinking and freeze-drying method. GO, as reinforcing filler, can be easily incorporated with SA matrix by self-assembly via hydrogen bonding interaction. Compared with pure SA aerogel, the as-prepared SAGO exhibited excellent mechanical strength and elasticity, and the compression strength of SAGO can reach up to 324 kPa and remain 249 kPa after five compression cycles when 4wt% GO was added, which were considered significant improvements. SEM result presents that the addition of GO obviously improves the porous structures of aerogel, which is beneficial for the enhancement of strength-toughness and adsorbability. As a consequence, the adsorption process of SAGO is better described by pseudo-second-order kinetic model and Langmuir isotherm, with maximum monolayer adsorption capacities of 98.0 mg/g for Cu2+ and 267.4 mg/g for Pb2+, which are extremely high adsorption capacities for metal ions and show far more promise for application in sewage treatment. (C) 2015 Elsevier B.V. All rights reserved.