▎ 摘　　要

A combined high-resolution X-ray photoelectron spectroscopy (HR-XPS) and ab initio density functional theory study on graphene on Ni(111) shows the coexistence of two structures, a bridge-top and a top-fcc structure, that have almost identical energies according to DFT calculations. Consequently, both geometries are detected simultaneously on the Ni(111) surface by HR-XPS, while their relative fractions depend on minor surface defect concentrations (pinning sites). The two structures are identified due to their different core level shifts that are in line with DFT calculations.