• 文献标题:   Incorporation of graphene into SnO2 photoanodes for dye-sensitized solar cells
  • 文献类型:   Article
  • 作  者:   BATMUNKH M, DADKHAH M, SHEARER CJ, BIGGS MJ, SHAPTER JG
  • 作者关键词:   photovoltaic, dyesensitized solar cell, photoanode, tin dioxide, graphene
  • 出版物名称:   APPLIED SURFACE SCIENCE
  • ISSN:   0169-4332 EI 1873-5584
  • 通讯作者地址:   Flinders Univ S Australia
  • 被引频次:   16
  • DOI:   10.1016/j.apsusc.2016.06.146
  • 出版年:   2016

▎ 摘  要

In dye-sensitized solar cell (DSSC) photoanodes, tin dioxide (SnO2) structures present a promising alternative semiconducting oxide to the conventional titania (TiO2), but they suffer from poor photovoltaic (PV) efficiency caused by insufficient dye adsorption and low energy value of the conduction band. A hybrid structure consisting of SnO2 and reduced graphene oxide (SnO2-RGO) was synthesized via a microwave assisted method and has been employed as a photoanode in DSSCs. Incorporation of RGO into the SnO2 photoanode enhanced the power conversion efficiency of DSSC device by 91.5%, as compared to the device assembled without RGO. This efficiency improvement can be attributed to increased dye loading, enhanced electron transfer and addition of suitable energy levels in the photoanode. Finally, the use of RGO addresses the major shortcoming of SnO2 when employed as a DSSC photoanode, namely poor dye adsorption and slow electron transfer rate. (C) 2016 Elsevier B.V. All rights reserved.