• 文献标题:   Green and facile edge-oxidation of multi-layer graphene by sodium persulfate activated with ferrous ions
  • 文献类型:   Article
  • 作  者:   HAN LJ, ZONG YX, TANG Q, WANG HR, LANG XR, CAO L, ZONG CZ
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:  
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.1039/d0ra05575a
  • 出版年:   2020

▎ 摘  要

Effective edge oxidation of graphene with high structural integrity is highly desirable yet technically challenging for most practical applications. In this work, we have developed a green and facile strategy to obtain edge-oxidized graphene with good dispersion stability and high electrical conductivity by exploiting high edge reactivity of highly conductive multi-layer graphene and oxidizing radicals (SO4-) generated from sodium persulfate (Na2S2O8) with ferrous ion (Fe2+) activation. Owing to high structural integrity of pristine graphene and effective edge oxidation, the obtained edge-oxidized graphene exhibited excellent dispersion stability and satisfactory electrical conductivity (i.e.>= 240 S cm(-1)). Moreover, the oxidation degree of pristine graphene can be well controlled by adjusting treatment time. The obtained edge-oxidized graphene is expected to find a variety of applications in many fields of anti-static films, energy storage materials, flexible sensors and high-performance nanocomposites.