• 文献标题:   Low-Temperature Thermal Reduction of Graphene Oxide Nanobrick Walls: Unique Combination of High Gas Barrier and Low Resistivity in Fully Organic Polyelectrolyte Multilayer Thin Films
  • 文献类型:   Article
  • 作  者:   STEVENS B, DESSIATOVA E, HAGEN DA, TODD AD, BIELAWSKI CW, GRUNLAN JC
  • 作者关键词:   layerbylayer assembly, oxygen barrier, thin film, reduced graphene oxide, sheet resistance
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Texas A M Univ
  • 被引频次:   29
  • DOI:   10.1021/am502889w
  • 出版年:   2014

▎ 摘  要

Layer-by-layer assembly from aqueous solutions was used to construct multilayer thin films (<200 nm) comprising polyethylenimine and graphene oxide. Low-temperature (175 degrees C) thermal reduction of these films improved gas barrier properties (e.g., lower permeability than SiOx), even under high humidity conditions, and enhanced their electrical conductivity to 1750 S/m. The flexible nature of the aforementioned thin films, along with their excellent combination of transport properties, make them ideal candidates for use in a broad range of electronics and packaging applications.