• 文献标题:   A new graphene nanocomposite modified electrode as efficient voltammetric sensor for determination of eriocitrin
  • 文献类型:   Article
  • 作  者:   WANG L, WANG QQ, SHENG K, LI GP, YE BX
  • 作者关键词:   cerium oxide nanopartide, graphene, poly diallyldimethylammonium chloride, electrochemical sensor, eriocitrin
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   5
  • DOI:   10.1016/j.jelechem.2016.11.061
  • 出版年:   2017

▎ 摘  要

A new grapherie nanocomposite, CeO2-poly(diallyldimethylammonium chloride)-graphene (CeO2-PDDA-GR), was prepared by an easy and low-cost hydrothermal method. The images of transmission electron microscopy (TEM) showed that well-shaped CeO2 nanoparticles distributed more uniformly on the GR sheets. Based on the CeO2-PDDA-GR composites modified glassy carbon electrode, the electrochemical properties of eriocitrin were investigated in detail and a sensitive determination method was established synchronously. Differential pulse voltammetry (DPV) measurement revealed that the oxidation peak current increased linearly with eriocitrin concentrations in range of 1.0 x 10(-8) mol x 10(-8) mol L-1 with detection limit of 7.0 x 10(-10) mol L-1 (S/N = 3). Moreover, the proposed method was used in determination of eriocitrin in lemon sample with accurate results. (C) 2016 Elsevier B.V. All rights reserved.