• 文献标题:   Porous alpha-Fe2O3 nanorods supported on carbon nanotubes-graphene foam as superior anode for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN MH, LIU JL, CHAO DL, WANG J, YIN JH, LIN JY, FAN HJ, SHEN ZX
  • 作者关键词:   iron oxide, graphene foam, carbon nanotube, electrochemical energy storage, lithium ion battery
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855 EI 2211-3282
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   157
  • DOI:   10.1016/j.nanoen.2014.08.011
  • 出版年:   2014

▎ 摘  要

A novel flexible and lightweight Fe2O3-based lithium-ion battery anode has been developed by growing porous alpha-Fe2O3 nanorods onto carbon nanotubes-graphene foam (CNT-GF). The CNT-GF 3D network provides a highly conductive, high surface areas and lightweight scaffold for the active Fe2O3 nanorods. Such unique electrodes for lithium-ion battery exhibit an 80% initial columbic efficiency, high-rate capabilities, and >1000 mA h/g capacities at 200 mA/g up to 300 cycles without obvious fading. These properties can be attributed to the fast electrochemical reaction kinetics and electron transport rendered by the conductive 3D network. Our structural design protocol can be extended to many other nanostructured metal oxides or sulfides, and thus provides a new strategy for construction of high-performance electrodes for energy storage. (C) 2014 Elsevier Ltd. All rights reserved.