• 文献标题:   Green Preparation of High Yield Fluorescent Graphene Quantum Dots from Coal-Tar-Pitch by Mild Oxidation
  • 文献类型:   Article
  • 作  者:   LIU QR, ZHANG JJ, HE H, HUANG GX, XING BL, JIA JB, ZHANG CX
  • 作者关键词:   graphene quantum dot, coal tar pitch, luminescence, green
  • 出版物名称:   NANOMATERIALS
  • ISSN:   2079-4991
  • 通讯作者地址:   Henan Polytech Univ
  • 被引频次:   6
  • DOI:   10.3390/nano8100844
  • 出版年:   2018

▎ 摘  要

Coal tar pitch (CTP), a by-product of coking industry, has a unique molecule structure comprising an aromatic nucleus and several side chains bonding on this graphene-like nucleus, which is very similar to the structure of graphene quantum dots (GQDs). Based on this perception, we develop a facile approach to convert CTP to GQDs only by oxidation with hydrogen peroxide under mild conditions. One to three graphene layers, monodisperse GQDs with a narrow size distribution of 1.7 +/- 0.4 nm, are obtained at high yield (more than 80 wt. %) from CTP. The as-produced GQDs are highly soluble and strongly fluorescent in aqueous solution. This simple strategy provides a feasible route towards the commercial synthesis of GQDs for its cheap material source, green reagent, mild condition, and high yield.