• 文献标题:   Graphene Oxide Functionalized Zn(II) Salen Complex: An Efficient and New Route for the Synthesis of 1,2,3-Triazole Derivatives
  • 文献类型:   Article
  • 作  者:   GHADAMYARI Z, KHOJASTEHNEZHAD A, SEYEDI SM, TAGHAVI F, SHIRI A
  • 作者关键词:   azidealkyne cycloaddition, zinc, schiff base 1, 2, 3triazole, click chemistry
  • 出版物名称:   CHEMISTRYSELECT
  • ISSN:   2365-6549
  • 通讯作者地址:   Ferdowsi Univ Mashhad
  • 被引频次:   0
  • DOI:   10.1002/slct.202002708
  • 出版年:   2020

▎ 摘  要

In this study, for the first time, the functionalized organometallic graphene oxide (GO) catalyst was prepared by covalently grafting of the Schiff base zinc complex on the surface of GO. The chemical and physical structures of the catalyst were completely characterized by different analyses such as FT-IR, TEM, EDX, TGA, XRD, SEM and ICP. Then, the applications of nano heterogeneous catalyst have been investigated for the synthesis of 1,2,3-triazolesviaazide-alkyne cycloaddition reaction. Although, synthesis of 1,2,3-triazoles derivatives has been reported by a wide variety of copper catalysts, this is the first report for the synthesis of 1,2,3-triazoles derivatives catalyzed by heterogeneous Schiff base zinc complex.