• 文献标题:   Flower-like spherical FeCoS2 coated by reduced graphene oxide as anode for high performance potassium ion storage
  • 文献类型:   Article
  • 作  者:   CHEN XY, CHENG N, ZHANG LS, XIANG GH, DING YL, LIU ZG
  • 作者关键词:   fecos2@rgo, potassium ion batterie, reduced graphene oxide, bimetallic sulfide, flowerlike sphere
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:  
  • 被引频次:   17
  • DOI:   10.1016/j.jallcom.2020.158458 EA JAN 2021
  • 出版年:   2021

▎ 摘  要

Bimetallic sulfides are regarded as promising electrode materials for potassium ion batteries owing to their attractive theoretical specific capacity, high redox activity, and environmental friendliness. However, undesirable agglomeration and inferior structural reversibility might result in their poor electrochemical performance and block their practical application. In this work, flower-like spherical FeCoS2 coated with reduced graphene oxide was prepared by a one-step hydrothermal synthesis method. As an anode material of potassium ion batteries, this flower-like spherical structure with extensive mesopores is conducive to the rapid penetration of electrolyte, thereby accelerating the transmission of potassium ions. Meanwhile, the encapsulation of reduced graphene oxide not only effectively reduces the structural deformation during the reaction, but also limits the aggregation of FeCoS2, which provides favorable conditions for improving the reversibility of the electrode material. As a result, it exhibits promising cycling stability (maintions 371 mAh g(-1) at 100 mA g(-1) after 150 cycles) and attractive rate performance (428 mAh g(-1) at 50 mA g(-1) and 248 mAh g(-1) at 1000 mA g(-1)). (C) 2020 Elsevier B.V. All rights reserved.