• 文献标题:   Probing permeation of energetic hydrogen atoms through molybdenum disulphide on graphene platform
  • 文献类型:   Article
  • 作  者:   RAVISHANKAR V, SHAINA PR, YADAV V, RAMAPRABHU S, JAISWAL M
  • 作者关键词:   hydrogenation, van der waals heterostructure, defect
  • 出版物名称:   MATERIALS RESEARCH EXPRESS
  • ISSN:   2053-1591
  • 通讯作者地址:   Indian Inst Technol Madras
  • 被引频次:   0
  • DOI:   10.1088/2053-1591/ab3170
  • 出版年:   2019

▎ 摘  要

Graphene and h-BN are known to be permeating for thermal protons, molybdenum disulphide (MoS2) is found to block them. We report permeation of highly energetic hydrogen atoms produced from electron beam irradiation of hydrogen silsesquioxane resist through MoS2 layers on graphene platform. Single-layer graphene has been used as a detector to estimate permeation. Extent of hydrogenation of graphene, estimated from Raman spectroscopy studies, was used to quantify the permeation of hydrogen atoms through monolayer, tri-layer and bulk MoS2. A decrease in defect density induced in graphene was observed with increasing layer numbers of MoS2. This data was used to estimate the absorption coefficient of MoS2 using the defect density n(D), with a value close to 0.06 angstrom(-1). The percentage transmission of hydrogen atoms was found to be 65% per layer.