▎ 摘　　要

Organic carbonyl polymers have been gradually used as the cathode in lithium-ion batteries (LIB). However, there are some limits in most organic polymers, such as low reversible capacity, poor rate performance, cycle instability, etc., due to low electrochemical conductivity. To mitigate the limits, we propose a strategy based on polyimide (PI)/graphene electroactive materials coated with reduced graphene oxide to prepare a flexible film (G@PI/RGO) by solvothermal and vacuum filtration processes. As a flexible cathode for LIB, it provides a reversible capacity of 198 mA h g(-1) at 30 mA g(-1) and excellent rate performance of 100 mA h g(-1) at high current densities of 6000 mA g(-1), and even a super long cycle performance (2500 cycles, 70% capacity retention). The excellent performance results in a special layer structure in which the electroactive PI was anchored and coated by the graphene. The present synthetic method can be further applied to construct other high-performance organic electrodes in energy storage.