• 文献标题:   One-step surface modification of graphene oxide and influence of its particle size on the properties of graphene oxide/epoxy resin nanocomposites
  • 文献类型:   Article
  • 作  者:   HUSKIC M, BOLKA S, VESEL A, MOZETIC M, ANZLOVAR A, VIZINTIN A, ZAGAR E
  • 作者关键词:   nanocomposite, epoxy, plasma, grapheneoxide, thermal propertie, mechanical propertie
  • 出版物名称:   EUROPEAN POLYMER JOURNAL
  • ISSN:   0014-3057 EI 1873-1945
  • 通讯作者地址:   Natl Inst Chem
  • 被引频次:   8
  • DOI:   10.1016/j.eurpolymj.2018.02.036
  • 出版年:   2018

▎ 摘  要

Graphene oxide (GO) was synthesized from expanded graphite with particle size of 130 mu m (GO130) and 1200 mu m (GO1200) and characterized. GO130 was oxidized to a higher degree and contained larger concentration of C=O bonds. After the synthesis, the GO was kept in a form of viscous slurry in methanol to prevent formation of graphite oxide. The slurry was mixed with a hardener and methanol was evaporated. The nano composites with GO content from 0.25 to 1.0 wt% were prepared by mixing the epoxy resin, hardener and hardener/GO mixture and cured. The particles were homogeneously distributed within the polymer matrix as observed by SEM on the plasma etched samples. The glass transition temperature increased from 81 degrees C to up to 90 degrees C. The Young's modulus increased by 35% and 30% with the addition of GO130 and GO1200, respectively, while the tensile strength increased for 10% only when GO1200 had been added. The optimum concentration of GO in the nanocomposite is from 0.25 to 0.50 wt%.