▎ 摘 要
A conventional solvothermal way was used to synthesize graphene oxide (GO)/BiOCl photocatalytic nanomaterials with enhanced photocatalytic performance. Due to the introduction of GO, there are intu-itive changes in morphology, indicating that GO can guide the growth of GO/BiOCl catalysts. The results of X-ray photoelectron spectroscopy (XPS) and Raman show that a strong chemical interaction occurs around GO and BiOCl. The results of trapping experiments show that 'O2- is the major active species. XPS analysis confirms that the 0.75% GO/BiOCl produces the highest level of oxygen vacancies (OVs). All the GO/BiOCl photocatalysts possess better photocatalytic properties than the neat BiOCl, and 0.5% GO/BiOCl exhibits the highest photoactivity. The photocatalytic activity of 0.5% GO/BiOCl composite for detoxification of rhodamine B (RhB) and tetracycline (TC) under visible light illumination is 4.6 and 6.3 times of that on the reference BiOCl, separately, the photocatalytic activity of 0.5% GO/BiOCl for detox-ication of perfluorooctanoic acid (PFOA) is 1.25 times of that of the single BiOCl under UV light illumina-tion, which can be credited to the high separation rate of carriers and the strong interaction between GO and BiOCl. Combining with the results, a separation and transfer mechanism of carriers was revealed.(c) 2023 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.