• 文献标题:   Nafion reinforced with polyacrylonitrile nanofibers/zirconium-graphene oxide composite membrane for direct methanol fuel cell application
  • 文献类型:   Article
  • 作  者:   SIGWADI R, MOKRANI T, MSOMI PF
  • 作者关键词:   fuel cell, nafion r, nanofiber, graphene oxide, proton conductivity
  • 出版物名称:   JOURNAL OF POLYMER RESEARCH
  • ISSN:   1022-9760 EI 1572-8935
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1007/s10965-021-02854-x
  • 出版年:   2022

▎ 摘  要

Electrospun polyacrylonitrile (PAN) nanofibers decorated with ZrO2 then blended with graphene oxide nanofibers were used to enhance the fuel cell performance and the conductivity of Nafion (R) membrane. The modified membranes and the commercial membrane were synthesized by recast method. Nanocomposite's membranes had higher proton conductivity and overall membrane properties increased, and fuel cell efficiency than commercial Nafion (R) and similar work published in the literature (R). The Nafion (R)-PAN/ZrO2-GO nanofiber membrane had a lower methanol permeability and a proton conductivity of 5.46 x 10(-8) cm(2)/s and 0.46 mS/cm, respectively, with a fuel cell performance of 75.9 mWcm(-2) at a current density of 250 mAcm(-2). The composite membrane used in this study has potential for use in fuel cells.