• 文献标题:   One-pot construction of 3-D nitrogen-doped activated graphene-like nanosheets for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   LI ZS, LI BL, LIU ZS, LI DH, WANG HQ, LI QY
  • 作者关键词:   3d structure, activated carbon, graphenelike nanosheet, nitrogen doping, supercapacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:   Guangdong Univ Petrochem Technol
  • 被引频次:   28
  • DOI:   10.1016/j.electacta.2015.12.210
  • 出版年:   2016

▎ 摘  要

Novel three-dimensional nitrogen-doped activated graphene-like nanosheets (3-D NAGNs) have been synthesized from inexpensive ion exchange resin, by using the an efficient activation-graphitization doping synchronous strategy. The 3-D NAGNs sample has been systematically characterized by the X-ray diffraction, Scanning electron microscope, Transmission electron microscopy, X-ray photoelectron spectroscopy and Nitrogen adsorption-desorption techniques. The analysis results indicate that the 3-D NAGNs has a high specific surface area of 1815.6 m(2) g (1), a desirable crystalline structure and a satisfactory nitrogen content of 3.62% in atomic ratio. The as-prepared 3-D NAGNs electrode demonstrates excellent electrochemical performances for supercapacitors in 6M KOH aqueous solution electrolyte. A considerable specific capacitance of 383.2 F/g is obtained for the 3-D NAGNs electrode via charge discharge at a current density of 1.0 A/g. It also displayed a very high cycle stability of 98%, compared with the initial capacitance, after 5000 cycles at a very high current density of 10 A/g. (C) 2015 Elsevier Ltd. All rights reserved.