• 文献标题:   Preparation of Polylactide/Graphene Composites From Liquid-Phase Exfoliated Graphite Sheets
  • 文献类型:   Article
  • 作  者:   LI XY, XIAO YH, BERGERET A, LONGEREY M, CHE JF
  • 作者关键词:  
  • 出版物名称:   POLYMER COMPOSITES
  • ISSN:   0272-8397 EI 1548-0569
  • 通讯作者地址:   Nanjing Normal Univ
  • 被引频次:   24
  • DOI:   10.1002/pc.22673
  • 出版年:   2014

▎ 摘  要

Polylactide (PLA)/graphene nanocomposites were prepared by a facile and low-cost method of solution-blending of PLA with liquid-phase exfoliated graphene using chloroform as a mutual solvent. Transmission electron microscopy (TEM) was used to observe the structure and morphology of the exfoliated graphene. The dispersion of graphene in PLA matrix was examined by scanning electron microscope, X-ray diffraction, and TEM. FTIR spectrum and the relatively low I-D/I-G ratio in Raman spectroscopy indicate that the structure of graphene sheets (GSs) is intact and can act as good reinforcement fillers in PLA matrix. Thermogravimetric analysis and dynamic mechanical analysis reveal that the addition of GSs greatly improves the thermal stability of PLA/GSs nanocomposites. Moreover, tensile strength of PLA/GSs nanocomposites is much higher than that of PLA homopolymer, increasing from 36.64 (pure PLA) up to 51.14 MPa (PLA/GSs-1.0). POLYM. COMPOS., 35:396-403, 2014. (c) 2013 Society of Plastics Engineers