• 文献标题:   Formation of misfit dislocation arrays and helium nanochannels near copper surface assisted by high-temperature graphene deposition
  • 文献类型:   Article
  • 作  者:   YANG K, LIU G, MA HY, SONG J, LI Q, CHEN N, WANG Y, CHEN D, LIU Y, FAN T
  • 作者关键词:   misfit dislocation array, graphene, copper interface, semicoherent interface, surface energy, helium nanochannel
  • 出版物名称:   ACTA MATERIALIA
  • ISSN:   1359-6454 EI 1873-2453
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.1016/j.actamat.2022.118134 EA JUL 2022
  • 出版年:   2022

▎ 摘  要

Misfit dislocation arrays (MDAs) at semi-coherent heterogeneous interface have been demonstrated ef-fectiveness to trap and then outgas helium (He) for alleviating void swelling in metals, but limited by atomic-level thin film deposition that is difficult to scale-up for industrial production. In this work, we proposed an innovative strategy that could generate semi-coherent homophase interfaces in a same grain by varying surface energy density assisted by high-temperature graphene (Gr) deposition. This strategy transforms strain energy and surface energy, two originally distinctive processes into successive pro-cesses, and demonstrates experimentally and theoretically by introducing {111} copper (Cu) in a {100} Cu grain. Subsequent He implantation and electrical resistivity measurement results suggest that high -density MDAs originated at this {111}/{100} interface could form stable He nanochannels near Cu surface with Gr assistance, manifesting by ultra-low increased ratio of the electrical resistivity (i.e.-3800% of Cu vs.-90% of Gr/Cu) after He implantation. The present findings may provide a new strategy for efficiently managing He and achieving surface protection of advanced metals, merely by depositing a super-rigid material on metal surface to greatly reduce surface energy density.(c) 2022 Acta Materialia Inc. Published by Elsevier Ltd. All rights reserved.