• 文献标题:   Synthesis of new mixed metal oxide RuNi2O4 phase decorated on reduced graphene oxide for supercapacitor applications
  • 文献类型:   Article
  • 作  者:   BERA S, MIAH M, MONDAL TK, DEBNATH A, SAHA SK
  • 作者关键词:   pristine runi2o4, runi2o4/rgo composite, graphene, high specific capacitance
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.electacta.2022.140666 EA JUN 2022
  • 出版年:   2022

▎ 摘  要

Design and fabrication of high performance energy storage devices using different mixed metal oxides decorated on conducting 2D surfaces are being investigated intensively now a days. In the present work, we have explored to synthesize a new mixed metal oxide (RuNi2O4) containing Ru and Ni and decorate the nanoparticles of these mixed metal oxides on highly conducting 2D reduced graphene oxide (rGO) surfaces to prepare efficient electrodes for high performance supercapacitors. The microstructure and compositional analyses of the composite structure are carried out by powder X-ray diffraction (XRD), transmission electron microscope (TEM) and X-ray photoelectron spectroscopy (XPS). The XRD data have been analysed by Rietveld refinement. The electrochemical performance of the device has been investigated via galvanostatic charging-discharging (GCD), cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS) analyses. It is seen that RuNi2O4/rGO composite shows a very high specific capacitance of 792 Fg(-1) compared to the values of rGO and pristine RuNi2O4 as 235 and 367 Fg(-1), respectively. Due to the combined effect of the electric double layer contribution of rGO and the faradaic contribution of RuNi2O4, RuNi2O4/rGO composite results in this high value of specific capacitance in the composite structure.