• 文献标题:   One-pot solvothermal synthesis of CoNi2S4/reduced graphene oxide (rGO) nanocomposites as anode for sodium-ion batteries
  • 文献类型:   Article
  • 作  者:   XU TT, ZHAO JH, YANG JX, CHEN JJ, WU YD, XU JL
  • 作者关键词:   sodiumion batterie, coni2s4, reduced graphene oxide, nanocomposite, anode material
  • 出版物名称:   IONICS
  • ISSN:   0947-7047 EI 1862-0760
  • 通讯作者地址:   Shanghai Univ Engn Sci
  • 被引频次:   1
  • DOI:   10.1007/s11581-019-03194-z
  • 出版年:   2020

▎ 摘  要

In this study, CoNi2S4 were successfully grown on reduced graphene oxide (rGO) by a simple one-pot solvothermal process, and applied to anode materials for sodium-ion batteries (SIBs) for the first time. The structural features and components of the obtained CoNi2S4/rGO were characterized by a series of testing methods. The electrochemical performances testing results suggested that the sodium storage performances of the CoNi2S4/rGO nanocomposites were enhanced dramatically compared with pure CoNi2S4. The CoNi2S4/rGO anode expresses an excellent reversible capacity of 430 mAh g(-1) after 50 cycles at 100 mA g(-1). The CoNi2S4/rGO electrode still shows a reversible capacity of 521 mAh g(-1) when the current density grows to 1000 mA g(-1). The enhancement of electrochemical performances is due to the addition of rGO, which can effectively buffer volume variations and improve electrical conductivity during charge-discharge process. The CoNi2S4/rGO nanocomposites can be a promising anode material for SIBs.