• 文献标题:   Nitrogen-doped graphene supported Pt nanoparticles with enhanced performance for methanol oxidation
  • 文献类型:   Article
  • 作  者:   MA JH, WANG L, MU X, LI L
  • 作者关键词:   polyaniline, graphene, nitrogendoped, platinum electrocatalyst, methanol oxidation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Xinjiang Univ
  • 被引频次:   46
  • DOI:   10.1016/j.ijhydene.2014.12.080
  • 出版年:   2015

▎ 摘  要

A series of nitrogen-doped graphene nanocomposites (N-RGO) derived from pyrolysis of graphene oxide (GO)/polyaniline composites with varied mass ratio between GO and aniline were used as support for immobilization of Pt nanoparticles. Transmission electron microscopy, X-ray powder diffraction, Raman spectroscopy and X-ray photoelectron spectroscopy were used to characterize the morphology and microstructure of the prepared catalysts. The catalytic activity of the catalysts towards the oxidation of methanol was evaluated by cyclic voltammetry. Compared to the undoped Pt/RGO catalyst, an enhanced electrocatalytic activity for methanol oxidation was obtained in the case of the Pt/N-RGO with optimized composition and nanostructure. Copyright (C) 2015, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.