• 文献标题:   Effect of Gold Substrates on the Raman Spectra of Graphene
  • 文献类型:   Article
  • 作  者:   KIM N, OH MK, PARK S, KIM SK, HONG BH
  • 作者关键词:   graphene, raman, gold, nanoparticle, surface enhanced raman scattering
  • 出版物名称:   BULLETIN OF THE KOREAN CHEMICAL SOCIETY
  • ISSN:   0253-2964
  • 通讯作者地址:   Sungkyunkwan Univ
  • 被引频次:   23
  • DOI:   10.5012/bkcs.2010.31.04.999
  • 出版年:   2010

▎ 摘  要

Raman spectra of a single layer graphene sheet placed in different gold substrates were obtained and are discussed in the context of surface enhanced Raman scattering (SERS) The gold substrates were composed of a combination of a thermally deposited gold film and a close-packed gold nanosphere layer The SERS effects were negligible when the excitation wavelength was 514 nm, while the Raman signals were enhanced 3- to 50-fold when the excitation wavelength was 633 nm The large SERS enhancement accompanied a spectral distortion with appearance of several unidentifiable peaks, as well as enhancement of a broadened D peak. These phenomena are interpreted as the local field enhancement in the nanostructure c of the gold substrates The difference in the enhancement factors among the various gold substrates is explained with a model in which the spatial distribution and polarization of the local field and the orientation of the inserted graphene sheet are considered important