• 文献标题:   A facile approach to fabricate few-layer chemically modified and reduced graphene oxide sheets: Combination of stitching, reduction and functionaliztion
  • 文献类型:   Article
  • 作  者:   FAN K, LI JH, LI LF, LI JY
  • 作者关键词:   graphene oxide, linear diaminoalkane, reduction functionaliztion, fewlayer
  • 出版物名称:   FULLERENES NANOTUBES CARBON NANOSTRUCTURES
  • ISSN:   1536-383X EI 1536-4046
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   3
  • DOI:   10.1080/1536383X.2017.1398738
  • 出版年:   2018

▎ 摘  要

A facile strategy for the preparation of few-layer chemically stitched and reduced graphene oxide (FL-CMRG) in water using various linear diaminoalkanes with the general formula H2N(CH2) nNH(2) (n = 4, 6, 8) is proposed, and the resulting FL-CMRG was characterized by means of AFM, TEM, XPS, UV-vis, TGA and XRD. Interlayer spacing between bridged FL-CMRG sheets can reach 1.038 nm when the size of the intercalant to (n = 6) H2N (CH2)(6) NH2. A mechanism for forming the FL-CMRG via removal of epoxide and hydroxyl groups from GO and stitching of the GO sheets by various linear diaminoalkanes in water solution has been proposed.