• 文献标题:   Combined experimental and theoretical studies on enlarged bandgap and improved photoelectrochemical properties of reduced graphene oxide film by hydrogen annealing
  • 文献类型:   Article
  • 作  者:   KHAI TV, HAI LV, HA NTT, THOM NT, TRANG NV, NAM PT, HA NN, LAM TD
  • 作者关键词:   reduced graphene oxide rgo, thermal annealing, enlarged bandgap, electrical conductivity, photoelectrochemical pec propertie, theoretical calculation, sp 2 domain
  • 出版物名称:   JOURNAL OF ELECTROANALYTICAL CHEMISTRY
  • ISSN:   1572-6657 EI 1873-2569
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.jelechem.2021.115722 EA SEP 2021
  • 出版年:   2021

▎ 摘  要

The effect of thermal annealing on the recovery of sp2 carbon networks in the reduced graphene oxide (RGO) and its consequent bandgap enlargement and electrical conductivity improvement were thoroughly studied, experimentally and theoretically correlated. The annealed RGO film at 1100 degrees C (designated as RGO1100) exhibited a low sheet resistance (1250 Omega.cm-2) with a wide bandgap of 2.82 eV. The photoelectrochemical (PEC) experiments in 1 M H2SO4 solution under solar simulation light (1.5 AM) showed photocurrent densities of 48 and 70 mu A.cm-2 for non-annealed RGO (72.5% sp2 fraction) and RGO1100 (87% sp2 fraction) respectively, equivalent to an increase of 45.8% for RGO1100. The bandgap widening as well as electrical conductivity increase of RGO1100 were closely interpreted on the basis of sp2 domain restoration, electronic and molecular orbital structures obtained from extensive experimental data as well as elaborated Geometry, Frequency, Noncovalent Extended Tight-binding (GFN2-xTB) and simplified Tamm-Dancoff density functional theory (sTD-DFT) calculations. The correlation between the electronic structure and the PEC performance of the RGO was also evaluated when the impact of the spatial distribution of oxidation and reduction regions on the recombination rate between photogenerated electrons and holes had been taken into account. The findings shed light on the structure-PEC relationship of RGO1100, which will definitely assist in designing and tailoring RGO-based, highly active materials for PEC applications.