• 文献标题:   Electrical Conductivity and Mechanical Properties of Ionic Liquid Modified Shear Exfoliation Graphene/CO-PA Nanocomposites at Extremely Low Graphene Loading
  • 文献类型:   Article
  • 作  者:   LIU X, WANG LY, WAN ZG, ZHAO LF, HE HF
  • 作者关键词:  
  • 出版物名称:   POLYMER COMPOSITES
  • ISSN:   0272-8397 EI 1548-0569
  • 通讯作者地址:   Shandong Univ Sci Technol
  • 被引频次:   2
  • DOI:   10.1002/pc.24016
  • 出版年:   2017

▎ 摘  要

In this study, the ionic liquid (IL) modified shear exfoliation graphene (SEG)/co-polyamide (IL-SEG/CO-PA) nanocomposites were fabricated by an effective and simple solution mixing method. In detail, SEG was fabricated in aqueous phase and then modified by IL, 1-butyl-3-methylimidazolium chloride (BMIMCL) to enhance its dispersion in CO-PA matrix. The IL-SEG/CO-PA nanocomposites were of good properties, such as thermal property, electrical conductivity and mechanical properties, especially a low percolation threshold of not higher than 0.15 wt% (about 0.0523 vol%). The tests and measurements indicated that the Tc, T-50%, and Td-max of the nanocomposites was 17 degrees C, 18 degrees C, and 22.5 degrees C higher than that of CO-PA respectively; when SEG content was 0.75 wt%, the electrical conductivity was improved from 2.85 x 10(-12) S/m to 1.32 x 10(-7) S/m, the tensile strength increased by 43.2%, and yield strength 19.7%. The incorporation of IL resulted in the good exfoliation and dispersion of graphene in CO-PA matrix, which could be the direct reason for the improvement of the nanocomposites. (C) 2016 Society of Plastics Engineers