• 文献标题:   Edge phonon state of mono- and few-layer graphene nanoribbons observed by surface and interference co-enhanced Raman spectroscopy
  • 文献类型:   Article
  • 作  者:   REN WC, SAITO R, GAO LB, ZHENG FW, WU ZS, LIU BL, FURUKAWA M, ZHAO JP, CHEN ZP, CHENG HM
  • 作者关键词:  
  • 出版物名称:   PHYSICAL REVIEW B
  • ISSN:   2469-9950 EI 2469-9969
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   49
  • DOI:   10.1103/PhysRevB.81.035412
  • 出版年:   2010

▎ 摘  要

Using surface and interference co-enhanced Raman scattering measurements, we detected two well-distinguished Raman bands at 1450 and 1530 cm(-1) from individual mono-and few-layer graphene nanoribbons (GNRs) prepared by chemical exfoliation and mechanical cleavage of graphite. The intensities of these two peaks strongly depend on the width and edge structure of the GNRs. Combining with first-principles calculations, the 1450 and 1530 cm(-1) Raman bands are assigned to the localized vibration of the edge atoms of zigzag and armchair GNRs terminated with H atoms, respectively. In addition, two weak peaks at similar to 1140 and 1210 cm(-1) are also observed, which are coupled with 1450 and 1530 cm(-1), respectively. These findings enrich the understanding on the fine structure of mono-and few-layer GNRs by Raman spectroscopy.