▎ 摘 要
Covalently anchored chromium complex on reduced graphene oxide (rGO-Cr) is successfully synthesised through trimethoxy silyl propanamine (TMSPA) and phenyl azo salicylaldehyde (PAS) coupling. The rGO-Cr is characterised by Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), electron dispersive analysis of X-rays (EDAX), Raman spectroscopy, scanning electron microscopy (SEM) and high resolution transmission electron microscopy (HRTEM). Absorption and emission properties of rGO-TMSPA-PAS are studied by excitation dependent photoluminescence emissions at room temperature. Electrochemical sensing activity of rGO-Cr is monitored for paracetamol using modified glassy carbon electrode. Cyclic voltammetry measurements indicated that rGO-Cr substantially enhance the eletrochemical response of paracetamol. The experimental factors are investigated and optimized.