• 文献标题:   Preparation of nickel and graphene modified La9CeMg80Ni5 composites and their microstructure and electrochemical properties
  • 文献类型:   Article
  • 作  者:   ZHANG W, YUAN ZM, ZHAO DL, LI J, HOU ZH, QI Y, ZHANG YH
  • 作者关键词:   electrochemical performance, mg based alloy, surface modification, ball milling, microstructure
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ijoes.2023.100177 EA APR 2023
  • 出版年:   2023

▎ 摘  要

A La2Mg17-type alloy La9CeMg80Ni5 was prepared and mechanically crushed to powders. Ni and Graphite (GR) were added during ball milling to prepare the surface-modified La9CeMg80Ni5-GR-Ni composites. The influence of milling time and Ni content on the structure and electrochemical properties of the composite materials were investigated. After milling, the composite materials are capable of electrochemically hydriding and dehydriding at room temperature. As Ni content increases, the 40 h-milled composites show an increased discharge capacity from 219.6 to 986.2 mAh/g, HRD from 75.3% to 86.8%, and capacity retention rate of 20th cycle from 58.2% to 65.8%; the 80 h-milled composites show an increased discharge capacity from 252.6 to 1034.7 mAh/g, HRD from 80.5% to 87.9%, and capacity retention rate of 20th cycle from 47.3% to 56.2%.