• 文献标题:   In-situ construction of Mn-Fe mixed oxides nanoparticles on reduced graphene oxide with superior lithium storage property
  • 文献类型:   Article
  • 作  者:   CHEN HY, SHEN XP, JI ZY, CHENG J, LIU GX, LANG LM, CHEN Y
  • 作者关键词:   graphene, synthesi, anode material, lithiumion battery
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1016/j.ijhydene.2022.08.037
  • 出版年:   2022

▎ 摘  要

In this paper, porous Mn3O4-Fe3O4 nanoparticles with highly uniform composition are in -situ anchored on reduced graphene oxide (rGO) nanosheets by a simple cyanometallic framework template method. Thanks to the synergistic effects between the porous Mn3O4-Fe3O4 nanoparticles and the well-conductive rGO nanosheets, the Mn3O4-Fe3O4/rGO composites present superior electrochemical lithium storage performances with a great reversible capacity of 1013 mAh g-1 after 100 cycles at 0.1 A g-1, satisfactory rate capability of 510 mAh g-1at 3.0 A g-1, and eminent long-term cycle stability of 804 mAh g-1 after 500 cycles at 0.5 A g-1. It is demonstrated that the rGO can not only act as a conducting matrix, but also buffer the volume expansion and avoid the aggregation of the Mn3O4-Fe3O4 nanoparticles during charging-discharging. The work provides a simple strategy for designing and fabricating advanced multi-component metal oxide-based anodes for high-performance lithium-ion battery.(c) 2022 Hydrogen Energy Publications LLC. Published by Elsevier Ltd. All rights reserved.