• 文献标题:   3D Printed Graphene Electrodes Modified with Prussian Blue: Emerging Electrochemical Sensing Platform for Peroxide Detection
  • 文献类型:   Article
  • 作  者:   KATIC V, DOS SANTOS PL, DOS SANTOS MF, PIRES BM, LOUREIRO HC, LIMA AP, QUEIROZ JCM, LANDERS R, MUNOZ RAA, BONACIN JA
  • 作者关键词:   3d printed graphene electrode, electrodeposition, prussian blue, electrocatalysi, h2o2 detection
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Univ Estadual Campinas
  • 被引频次:   18
  • DOI:   10.1021/acsami.9b09305
  • 出版年:   2019

▎ 摘  要

3D printing technologies have been considered an important technology due to the ease manufacturing of objects, freedom of design, waste minimization, and fast prototyping. In chemistry, this technology potentializes the fabrication of conductive electrodes in large scale for sensing applications. Herein, we reported the modification of a 3D printed graphene electrode with Prussian blue. The modified electrode (3DGrE/PB) was characterized by microscopy (SEM and AFM) and spectroscopic techniques, and its electrochemical properties were compared to the traditional electrodes: glassy carbon, gold, and platinum. The 3DGrE/PB was used in the sensing of hydrogen peroxide in real-world samples of milk and mouthwash, and the results obtained according to the technique of batch-injection analysis were satisfactory for the concentration range typically found in such samples. Thus, 3DGrE/PB can be used as a new platform for sensing of molecular targets.